INDEX

acid, 4, 146, 183, 228, 429

acid-base reaction, 146, 197, 204, 232, 238, 292, 354

acidic hydrolysis, 180

acidic oxides, 173

acid–metal reaction, 275, 315

acid rain, 352

activation energy, 93, 105107 113, 134, 139, 154, 363, 367, 375, 383

addition polymer, 404

addition polymerization, 404, 417

addition reaction, 378, 390, 416

adsorption, 401

agent, 204

air, 422

alkalis, 183

allotropy, 68

alloy, 329, 330

alternative pathway, 112

amphoteric oxides, 173

anaerobic, 398

anions, 40, 43, 44

anode, 97, 243, 248, 256, 332

anodization, 281

atomic number, 25, 285

auto-ionization, 177, 257, 261, 264

Avogadro’s Law, 74, 90

back-titration experiment, 188

backward reaction, 133

base, 146, 183, 228, 429

basic hydrolysis, 180, 354

basicity, 174, 176

basic oxides, 173

bauxite ore, 278

bond, 43

bond-breaking, 24, 84, 93, 99

bond energy, 84, 96

bond-forming, 24, 99

bonding electrons, 40

bond-making, 93

Brine, 260

brittle, 45

bromothymol blue, 180, 181

Brønsted–Lowry, 174

Brønsted–Lowry Theory, 146

calorimeter, 92

capillary action, 419

carbon cycle, 359

carboxylic acids, 388

catalyst, 112, 142, 149, 367

catalytic converters, 103, 360, 361

catalytic cracking, 373, 374

cathode, 97, 243, 248, 256

cathodic prevention, 337

cathodic protection, 331

cation, 40, 43, 44, 53

chain isomerism, 392

change of state, 9, 11

charge carriers, 43, 61, 214

charge density, 173, 174, 231, 271, 294, 295, 320, 343

chemical bond, 2, 15, 42

chemical change, 1, 4, 5

chemical composition, 5

chemical energy, 255

chemical equation, 72, 73, 74, 222

chemical formula, 71

chemical passivation, 253, 317

chemical potential, 1

chemical property, 1, 5, 23

chemical reaction, 105

chemical reactivity, 23

chloride, 68

chlorofluorocarbon, 364

chromatogram, 419

closed system, 135

collisional frequency, 17

collision geometry, 112

Collision Theory, 105

composition stoichiometry, 73

compound, 5, 37, 38, 73

concentration gradient, 7

condensation, 413

condensation polymer, 413

condensation polymerization, 413

condensation reaction, 394

conjugate acid, 180, 184

conjugate base, 180, 354

constitutional formulae, 392

constitutional isomers, 392

coordinate bond, 46, 174

coordination number, 44, 55

Coulombic force, 25

covalent bond, 3941, 46, 48, 51, 84, 87

covalent bonding, 39

cracking, 373, 375

crude oil, 370

cryolite, 278, 334

dative covalent bond, 46, 174

dehydration, 253, 403

delocalized electrons, 40, 43, 52, 345

diagonal relationship, 289

diamond, 46, 67, 68

diffusion, 7

dimensionless, 27

dimerization, 141, 356

dipole moment, 50

dipoles, 49

discrete molecules, 48, 81

displacement reaction, 170, 234, 273, 308

disproportionation reaction, 210

distillate, 421

donor atom, 46

dot-and-cross diagram, 53

downward displacement of air, 428, 431

downward displacement of water, 427, 430, 431

ductility, 43

dynamic equilibrium, 10, 134

effective collisions, 105

effervescence, 171

electrical conductivity, 43, 57

electrical energy, 255

electrical neutrality, 121, 272

electric cell, 256

electrodes, 97, 256

electrolysis, 255, 269, 272, 338

electrolyte, 98, 250, 256

electrolytic cell, 255

electron cloud model, 41

electron deficient, 49, 50, 141, 173, 292, 294

electron density, 320

electronegativity, 30, 49, 51, 202, 203, 273, 288, 308

electronic configuration, 26, 32, 33, 36, 54, 341

electronic shell, 21, 22, 32, 29, 33, 287, 297

electron-rich, 49, 50, 173, 293, 294

electrons, 25

electrostatic force, 2

electron transfer, 147, 204

electroplating, 263

electropositivity, 30, 288

electrostatic, 94

electrostatic attractive force, 14, 2123, 25, 30, 42, 44, 51, 87, 312, 340, 341, 401

element, 5, 37, 38, 73

elimination, 413

empirical formula, 71, 78, 285, 410

endothermic, 24, 84, 86, 100, 134, 138, 139

endpoint, 180

energy change, 23, 48, 83, 85

energy content, 1, 88

energy level, 88

energy level diagram, 93, 136

energy profile diagram, 135, 136

enthalpy, 88

enthalpy change, 93, 142, 313

enzymes, 399, 400

equilibrium, 133, 138

equilibrium position, 138

esterification, 394

esters, 410

ethanoic acid, 406, 410

ethanol, 396, 398

exothermic, 85, 86, 88, 93, 99, 100, 134, 139

fermentation, 398, 406

filtrate, 424

flue-gas desulfurization, 103

formal charge, 202

forward reaction, 133

fossil fuels, 101, 102

fractional distillation, 369, 374, 421

frequency of collisions, 107, 130, 149

frequency of effective collisions, 108, 113, 155, 362, 367, 383

fuel cell, 97

fuels, 83

functional group isomerism, 392

galvanization, 331, 337

gasoline, 371

giant covalent lattice structure, 43, 199

giant covalent structure, 52

global warming, 102

graphite, 46, 67, 68, 280

greenhouse effect, 358

group number, 287, 296

Haber process, 148

half-equations, 207

heat change, 99

heat curve, 12

hematite, 325

heterogeneous catalysis, 113, 380

heterolytic cleavage, 374

homogeneous catalyst, 113

homolytic cleavage, 373, 374

hydrogenation, 114, 380

hydrogen bonding, 49, 307, 402, 408

hydrogen bonds, 69, 95, 396

hydrolysis, 183

hydronium ion, 175, 245

hydrophilic, 397

immiscible, 424

incomplete combustion, 102

independent variable, 125

induced dipole, 48

inert electrode, 258

inner-core electrons, 22, 33

instantaneous dipole, 48

instantaneous dipole–induced dipole interactions, 48, 52, 214, 307

inter-electronic repulsion, 22, 36, 66, 87, 96, 106

inter-ionic separation, 45

intermolecular bonding, 50

intermolecular forces, 42, 63, 66, 69, 75, 214, 286, 312, 422

intermolecular forces, 48

inter-nuclei region, 40

intramolecular bonds, 112

intramolecular covalent bonds, 60, 271, 295

iodine–thiosulfate titration, 162

ion-dipole, 199

ionic bond, 40, 43, 45, 51, 55

ionic bonding, 39

ionic equation, 121, 207

irreversible, 1, 133

isoelectronic, 36, 45, 66, 210

isomerism, 392

isomers, 392

isotopes, 26

isotopic composition, 56

kinetic energy, 12, 15, 84, 106, 113, 301, 422

Kinetic Particle Theory, 13

Kinetic Theory, 301

Kinetic Theory of Matter, 15

latent heat of vaporization, 16

Law of Conservation of Energy, 11, 15

Law of Conservation of Mass, 73

Le Chatelier’s Principle, 138, 140, 144, 152, 195

limiting reagent, 73

liquefaction of gas, 3

litmus paper, 429

lone pair of electrons, 50

macromolecular, 72

macromolecules, 404

malleability, 43

man-made pollutants, 102

mass concentration, 8

mass number, 25

Maxwell–Boltzmann distribution, 154

Maxwell–Boltzmann distribution curve, 109, 113

Maxwell–Boltzmann energy distribution, 106

metal, 41, 42, 55, 233

metallic bonding, 39, 52, 344

metallic bonds, 42, 57

metalloids, 29

metals, 29, 40, 286, 323

methyl orange, 181

minerals, 323

mixture, 5, 37

molar concentration, 8

molar mass, 77

molar volume, 75

molecular formula, 71, 73, 78, 285, 392, 410

monoatomic, 81

monomers, 404

naphtha, 371

neutralization, 183

neutral oxides, 173

neutrons, 25

noble gas, 28

non-biodegradable, 417

non-bonding electrons, 40

non-combustible hydrocarbons, 102

non-directional, 42

non-metal, 29, 4042, 54, 55, 286

non-metal oxide, 320

non-polar, 69, 100, 214, 307, 312

non-polar solvent, 59

nuclear charge, 22

nucleon number, 25

nucleons, 25, 27, 57

nuclide, 25

nylon, 413

octet configuration, 36, 141, 273, 307

octet rule, 31, 35, 46, 47, 54

oleum, 145

ore, 323

organic solvent, 313

oxidant, 147, 204

oxidation, 201, 243, 248, 256

oxidation half-equation, 207

oxidation number, 201, 202, 302

oxidation state, 201, 202, 290, 302, 321, 340

oxides, 173

oxidizing, 204

oxidizing agent, 97, 146, 147, 203, 227, 299, 340

oxidizing power, 233, 287, 308

paper chromatography, 419

partial, 49

partial negative charge, 49

particulate mass, 7

Periodic Table, 22

period number, 29, 287

permanent dipole–permanent dipole interactions, 49, 380

peroxides, 230

petrol, 371

phase, 113

phase transition, 10, 12

phenolphthalein, 180, 181

photosynthesis, 359

pH scale, 177

physical change, 1, 4

physical property, 1

point mass, 15

polar bonds, 49

polarizability, 55, 320

polarizing power, 231

polar molecules, 49

polyamide, 413, 414

polyester, 413

polymer, 404, 413

positional isomerism, 392

position of equilibrium, 139, 140, 150, 156

positive charge, 49

potential difference, 58, 65, 266

potential energy, 84

precipitate, 437

pressure, 17

progress of reaction, 136

proton acceptor, 146, 174

proton donor, 146, 174

proton number, 25

protons, 25

purification of copper, 262

qualitative analysis, 436

quenching, 161

radical, 375, 380

rate of diffusion, 7, 19

rate of reaction, 115, 117

reaction coordinate, 136

reaction stoichiometry, 73

reactivity series, 226, 230, 233, 234, 236, 249, 257, 324, 334, 338, 345, 349

redox, 210, 255

redox reaction, 147

reducing agent, 146, 147, 203, 204, 227

reducing power, 226, 233, 287, 340

reductant, 147, 204

reduction, 207, 243, 248, 256

reduction−oxidation, 112

relative atomic mass, 26, 285, 300

relative formula mass, 27

relative isotopic mass, 27

relative molecular mass, 27, 77

renewable energy, 103

repeat units, 416

reversible, 1, 133, 184

salt, 169

separating funnel, 424

shared electron, 30, 40, 51, 87, 94

shielding effect, 22

silicon dioxide, 46, 68

simple distillation, 421

slag, 325

sodium, 68

solute–solvent interactions, 377

spectator ions, 121

starch–iodine complex, 162

states of matter, 2

state symbol, 99

stoichiometry, 73

stratosphere, 365

strong, 180

strong acid, 174, 175, 197

strong acid–strong base, 181

strong acid–weak base, 181

strong base–weak acid titration, 180

structural formulae, 392

structural isomers, 392

sublimes, 420

substitution, 382

substitution reactions, 387

surroundings, 91

thermal conductivity, 333

thermal cracking, 373, 374

thermal insulation, 92

thermal pollution, 101

thermite reaction, 235

transition, 9

translational motion, 3

ultraviolet light, 362, 382

ultraviolet radiation, 315

upward displacement, 426

upward displacement of air, 430, 433

valence electrons, 21, 22, 26, 2931, 33, 39, 43, 51, 54, 287, 292, 296, 306, 321, 339, 340

valence shell, 42, 186, 229, 297

van der Waals’ forces, 48, 52

volatility, 312

water of crystallization, 199, 237

weak acid, 175, 179, 197, 315

weak acid–strong base, 181

weak acid–weak base, 181

weak base, 180, 184

weak base-strong acid titration, 180

weighted average quantity, 27

working range, 181