Interest in the elements and the periodic table has never been greater. Of course, we were all exposed to the periodic table at some point in school chemistry. Everybody remembers the chart that hung on the wall of the chemistry lab or classroom – parts of which we may even have been forced to learn by heart. The chart classifies all the known elements, those most fundamental components that make up the whole earth – and, indeed, the whole universe as far as we know.
But perhaps we didn’t appreciate at the time that the periodic table is without doubt one of the most important scientific discoveries ever made and is fundamental to our knowledge of chemistry today. The core idea is deceptively simple – arrange the elements in order of increasing weight of their atoms and every so often we arrive at an element that shows chemical and physical similarities with a previous one. This doesn’t just happen occasionally in the periodic table but is true of every single element except the very first few, which, of course, have no earlier counterparts in terms of atomic weight.
Dmitri Mendeleev
Russian chemist Dmitri Mendeleev was the first to propose the periodic table of elements as we know it now, as well as predicting the existence of some undiscovered elements. He is commonly referred to as the father of the peroidic table.
As a result of this behaviour, the linear sequence of elements can be arranged in a two-dimensional grid or ‘table’, much like a calendar that shows the recurring days of the week for certain dates in a given month. In this way, the tremendous variety among the elements is brought together into a coherent and interrelated form. Of course, these days we use atomic number (number of protons) to order the elements. But although this has solved a technical problem called ‘pair reversals’, it does not change the periodic table in any major fashion.
Mendeleev’s table, 1871
Antoine Lavoisier’s 1789 catalogue of elements formed the basis for the modern list, but it was not until Mendeleev’s early arrangement in 1869 and final proposal in 1871 that the periodic table was born.
At the time Russian chemist Dmitri Mendeleev and a number of others discovered the periodic system, there was no underlying explanation, no apparent reason why the elements should hang together in this way. But the very fact that all the elements could be successfully accommodated into such an elegant system seemed to suggest deeper things to come. Mendeleev was able to use the periodic table to predict the existence of elements that had never been found before. Within about 15 years, three of his best-known predictions came to be. The discovery of gallium, scandium, and germanium solidified the notion that the periodic system had latched onto a deep truth about the relationship between the chemical elements.
Around the turn of the 20th century many physicists – including J.J. Thomson, Niels Bohr and Wolfgang Pauli – set about trying to understand what lies behind the periodic system. British physicist Thomson, the discoverer of the electron, was one of the first to suggest that the electrons in an atom are arranged in a specific manner that we now call an electronic configuration. Danish physicist Niels Bohr refined these configurations and provided what remains the gist of the explanation for why elements, in fact, repeat every so often, or to put it another way, why it is that certain elements fall into particular groups or vertical columns in the periodic table. Bohr’s answer was that the elements in any vertical column share the same number of outer electrons, building on the emerging notion that chemical reactions are driven by outer electrons.
Next, Austrian physicist Wolfgang Pauli provided a further refinement to the notion of electronic configurations by suggesting that electrons have a hitherto unknown degree of freedom, which became known as ‘spin’. To put it in a nutshell, attempts to understand the periodic system contributed enormously to the development of quantum theory and these quantum ideas, in turn, provided a theoretical foundation for the periodic system of the elements.
Radioactive research
Pierre and Marie Curie gave their lives in pursuit of discovery, living in poverty to fund their research. Their perilous study of the radioactive elements has since contributed to the understanding of modern nuclear physics.
This book will take you on a short and highly digestible tour of 50 of the best known, as well as most intriguing, elements in the periodic table. They range from soft metals, such as sodium, that can be cut with a knife, to the magnificent liquid metal called mercury, to the poisonous gas chlorine that was the world’s first chemical weapon.
Each episode is delivered in just 30 seconds and is presented by the world’s leading experts on the elements with a proven track record for successfully explaining science to a general audience. You will also learn about the historical figures connected with each of the elements, perhaps as the first to have extracted them – or the first to think they had extracted them because there have been many, many dead ends and failed announcements of the discovery of a good number of the elements.
If condensing an account of each element to 30 seconds were not enough, you will also be provided with a 3-second summary plus a 3-minute version to ponder upon. You will read about the practical applications of the elements, their role in history and how they were first discovered. In some cases, you will read about the disputes that took place before they were eventually discovered or created in particle accelerators. You will learn how each element has its own unique ‘personality’, even though their atoms ultimately all boil down to different numbers of protons, neutrons and electrons. The chemistry of the elements essentially reduces to the physics of fundamental particles and yet something seems to defy complete reduction. Why else would the elements show such marked individuality while at the same time conforming to the basic physical laws imposed at the quantum mechanical level?
One is reminded of the amazing diversity in the animal kingdom, all of which sprang from one primordial creature. Evolution has also happened in chemistry, providing another facet to the story of the elements. In this case, the earliest form is still with us today. It is the element hydrogen, which still accounts for more than 75 per cent of the mass of the universe. All the other elements have come from hydrogen, directly or mostly indirectly by the fusion of lighter elements that themselves have their origin in hydrogen. Some parts of this astrophysical synthesis took place soon after the Big Bang, while other elements continue to be formed at the centre of stars and galaxies. The heavier elements, by which I mean anything heavier than iron (atomic number 26), are formed under extreme conditions in supernova explosions.
As somebody who has spent a lifetime studying the elements and the periodic table, I am both humbled and proud to have been the consulting editor and to have contributed to this entertaining and informative tour de force on man’s new best friends – the elements.
All that glitters …
Carbon, found in its most common form as graphite, may seem unappealing, but as one of its other many allotropes, as diamond, it is a much sought-after element.
The Periodic Table
The Periodic Table is organized by atomic number, electron configuration and recurring chemical properties. The rows of the table are called periods, and the columns are known as the groups. First proposed in 1869 with just 60 elements, the table has expanded to accommodate the 118 elements we now know of.
