Review Problems

  1. Within one principal quantum level of a many-electron atom, which orbital has the minimum energy?

    1. s
    2. p
    3. d
    4. f
  2. Which of the following compounds possesses at least one σ bond?

    1. CH4
    2. C2H2
    3. C2H4
    4. All of the above
  3. In a double-bonded carbon atom

    1. hybridization between the s orbital and one p orbital occurs.
    2. hybridization between the s orbital and two p orbitals occurs.
    3. hybridization between the s orbital and three p orbitals occurs.
    4. no hybridization occurs between the s and p orbitals.
  4. The hybridizations of the carbon atom and the nitrogen atom in the ion CN are

    1. sp3 and sp3, respectively.
    2. sp3 and sp, respectively.
    3. sp and sp3, respectively.
    4. sp and sp, respectively.
  5. Which of the following hybridizations does the Be atom in BeH2 assume?

    1. sp
    2. sp2
    3. sp3
    4. None of the above
  6. Two atomic orbitals combine to form:

    1. a bonding molecular orbital.
    2. an antibonding molecular orbital.
    3. new atomic orbitals.
    1. I only
    2. I, II, and III
    3. III only
    4. I and II only
  7. Molecular orbitals can contain a maximum of

    1. 1 electron.
    2. 2 electrons.
    3. 4 electrons.
    4. 2n2 electrons, where n is the principal quantum number of the combining atomic orbitals.
  8. π bonds are formed by which of the following orbitals?

    1. Two s orbitals
    2. Two p orbitals
    3. One s and one p orbital
    4. All of the above
  9. How many σ bonds and π bonds are present in the following compound?

    1. 6 σ bonds and 1 π bond
    2. 6 σ bonds and 2 π bonds
    3. 7 σ bonds and 1 π bond
    4. 7 σ bonds and 2 π bonds
  10. The four C−H bonds of CH4 point toward the vertices of a tetrahedron. This indicates that the hybridization of a carbon atom is

    1. sp.
    2. sp2.
    3. sp3.
    4. none of the above.