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Index
Cover
Title Page
Table of Contents
Preface
About the Companion Website
1 Introduction
1.1 What is Thermodynamics?
1.2 Steam Engines
1.3 Heat Engines
1.4 Heat, Work and Energy
1.5 Energy and the First Law of Thermodynamics
1.6 The Second Law of Thermodynamics
1.7 Entropy
Further Reading
2 Concepts and Definitions
2.1 Fundamental Concepts from Newtonian Mechanics
2.2 Derived Quantities: Velocity and Acceleration
2.3 Postulates: Newton’s Laws
2.4 Mechanical Work and Energy
2.5 Thermodynamic Systems
2.6 Thermodynamic Properties
2.7 Steady State
2.8 Equilibrium
2.9 State and Process
2.10 Quasi-Equilibrium Process
2.11 Cycle
2.12 Solving Problems in Thermodynamics
2.13 Significant Digits and Decimal Places
Further Reading
Summary
Problems
3 Thermodynamic System Properties
3.1 Describing a Thermodynamic System
3.2 States of Pure Substances
3.3 Mass and Volume
3.4 Pressure
3.5 Temperature
3.6 Ideal Gas Equation
3.7 Absolute Temperature Scale
3.8 Modelling Ideal Gases
3.9 Internal Energy
3.10 Properties of Liquids and Solids
Further Reading
Summary
Problems
4 Energy and the First Law of Thermodynamics
4.1 Energy
4.2 Forms of Energy
4.3 Energy Transfer
4.4 Heat
4.5 Work
4.6 The First Law for a Control Mass
4.7 Enthalpy
4.8 Specific Heats
4.9 Specific Heats of Ideal Gases
4.10 Which should you use, cp or cv?
4.11 Ideal Gas Tables
4.12 Specific Heats of Liquids and Solids
4.13 Steady Mass Flow Through a Control Volume
4.14 The First Law for Steady Mass Flow Through a Control Volume
4.15 Steady Flow Devices
4.16 Transient Analysis for Control Volumes
Further Reading
Summary
Problems
5 Entropy
5.1 Converting Heat to Work
5.2 A New Extensive Property: Entropy
5.3 Second Law of Thermodynamics
5.4 Reversible and Irreversible Processes
5.5 State Postulate
5.6 Equilibrium in a Gas
5.7 Equilibrium – A Simple Example
5.8 Molecular Definition of Entropy
5.9 Third Law of Thermodynamics
5.10 Production of Entropy
5.11 Heat and Work: A Microscopic View
5.12 Order and Uncertainty
Further Reading
Summary
Problems
6 The Second Law of Thermodynamics
6.1 The Postulates of Classical Thermodynamics
6.2 Thermal Equilibrium and Temperature
6.3 Mechanical Equilibrium and Pressure
6.4 Gibbs Equation
6.5 Entropy Changes in Solids and Liquids
6.6 Entropy Changes in Ideal Gases
6.7 Isentropic Processes in Ideal Gases
6.8 Reversible Heat Transfer
6.9 T-S Diagrams
6.10 Entropy Balance for a Control Mass
6.11 Entropy Balance for a Control Volume
6.12 Isentropic Steady Flow Devices
6.13 Isentropic Efficiencies
6.14 Exergy
6.15 Bernoulli’s Equation
Further Reading
Summary
Problems
7 Phase Equilibrium
7.1 Liquid Vapour Mixtures
7.2 Phase Change
7.3 Gibbs Energy and Chemical Potential
7.4 Phase Equilibrium
7.5 Evaluating the Chemical Potential
7.6 Clausius–Clapyeron Equation
7.7 Liquid–Solid and Vapour–Solid Equilibria
7.8 Phase Change on P-v and T-v Diagrams
7.9 Quality
7.10 Property Tables
7.11 Van der Waals Equation of State
7.12 Compressibility Factor
7.13 Other Equations of State
Further Reading
Summary
Problems
8 Ideal Heat Engines and Refrigerators
8.1 Heat Engines
8.2 Perpetual Motion Machines
8.3 Carnot Engine
8.4 Refrigerators and Heat Pumps
8.5 Carnot Principles
Further Reading
Summary
Problems
9 Vapour Power and Refrigeration Cycles
9.1 Rankine Cycle
9.2 Rankine Cycle with Superheat and Reheat
9.3 Rankine Cycle with Regeneration
9.4 Vapour Refrigeration Cycle
Further Reading
Summary
Problems
10 Gas Power Cycles
10.1 Internal Combustion Engines
10.2 Otto Cycle
10.3 Diesel Cycle
10.4 Gas Turbines
10.5 Brayton Cycle
10.6 Brayton Cycle with Regeneration, Reheat and Intercooling
Further Reading
Summary
Problems
Appendices
Appendix 1: Properties of Gases
Appendix 2: Properties of Solids
Appendix 3: Properties of Liquids
Appendix 4: Specific Heats of Gases
Appendix 5: Polynomial Relations for Ideal Gas Specific Heat as a Function of Temperature
Appendix 6: Critical Properties of Fluids
Appendix 7: Ideal Gas Tables for Air
Appendix 8: Properties of Water
Appendix 9: Properties of R-134a
Appendix 10: Generalised Compressibility
Index
End User License Agreement
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