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Index
Cover Page
Title Page
Copyright Page
Contents
Preface
Preface to the First Edition
Acknowledgments
1 Importance of Process Design
1.1 Classification of Polymer Processes
1.2 Film Blowing: Case Study
1.3 Basics of Polymer Process Design
References
2 Isothermal Flow of Purely Viscous Non-Newtonian Fluids
Design Problem I Design of a Blow Molding Die
2.1 Viscous Behavior of Polymer Melts
2.2 One-Dimensional Isothermal Flows
2.3 Equations of Change for Isothermal Systems
2.4 Useful Approximations
2.5 Solution to Design Problem I
Problems
References
Notes
3 Viscoelastic Response of Polymeric Fluids and Fiber Suspensions
Design Problem II Design of a Parison Die for a Viscoelastic Fluid
3.1 Material Functions for Viscoelastic Fluids
3.2 Nonlinear Constitutive Equations
3.3 Rheometry
3.4 Useful Relations for Material Functions
3.5 Rheological Measurements and Polymer Processability
3.6 Solution to Design Problem II
Problems
References
Notes
4 Diffusion and Mass Transfer
Design Problem III Design of a Dry-Spinning System
4.1 Mass Transfer Fundamentals
4.2 Diffusivity, Solubility, and Permeability in Polymer Systems
4.3 Non-Fickian Transport
4.4 Mass Transfer Coefficients
4.5 Solution to Design Problem III
Problems
References
5 Nonisothermal Aspects of Polymer Processing
Design Problem IV Casting of Polypropylene Film
5.1 Temperature Effects on Rheological Properties
5.2 The Energy Equation
5.3 Thermal Transport Properties
5.4 Heating and Cooling of Nondeforming Polymeric Materials
5.5 Crystallization, Morphology, and Orientation
5.6 Solution to Design Problem IV
Notes
Problems
References
6 Mixing
Design Problem V Design of a Multilayered Extrusion Die
6.1 Description of Mixing
6.2 Characterization of the State of Mixture
6.3 Striation Thickness and Laminar Mixing
6.4 Residence Time and Strain Distributions
6.5 Dispersive Mixing
6.6 Thermodynamics of Mixing
6.7 Chaotic Mixing
6.8 Solution to Design Problem V
Problems
References
7 Extrusion Dies
Design Problem VI Coextrusion Blow Molding Die
7.1 Extrudate Nonuniformities
7.2 Viscoelastic Phenomena
7.3 Sheet and Film Dies
7.4 Annular Dies
7.5 Profile Extrusion Dies
7.6 Multiple Layer Extrusion
7.7 Solution to Design Problem VI
Problems
References
8 Extruders
Design Problem VII Design of a Devolatilization Section for A Single-Screw Extruder
8.1 Description of Extruders
8.2 Hopper Design
8.3 Plasticating Single-Screw Extruders
8.4 Twin-Screw Extruders
8.5 Mixing, Devolatilization, and Reactions in Extruders
8.6 Solution to Design Problem VII
Problems
References
9 Postdie Processing
Design Problem VIII Design of a Film Blowing Process for Garbage Bags
9.1 Fiber Spinning
9.2 Film Casting and Stretching
9.3 Film Blowing
9.4 Solution to Design Problem VIII
Problems
References
10 Molding and Forming
Design Problem IX Design of a Compression Molding Process
10.1 Injection Molding
10.2 Compression Molding
10.3 Thermoforming
10.4 Blow Molding
10.5 Solution to Design Problem IX
Problems
References
11 Process Engineering for Recycled and Renewable Polymers
11.1 Life-Cycle Assessment
11.2 Primary Recycling
11.3 Mechanical or Secondary Recycling
11.4 Tertiary or Feedstock Recycling
11.5 Renewable Polymers and Their Processability
Problems
References
Nomenclature
Appendix A Rheological Data for Several Polymer Melts
A.1 Ldpe Data
A.2 Hdpe Data
A.3 Lldpe Data
A.4 Nylon 6, 6 Data
A.5 Pps Data
Appendix B Physical Properties and Friction Coefficients for Some Common Polymers in the Bulk State
Appendix C Thermal Properties of Materials
Appendix D Conversion Table
Index
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