Geofluids, Developments in Microthermometry, Spectroscopy, Thermodynamics, and Stable Isotopes by Hurai, Vratislav -- Read -- Imperial Library of Trantor

Index

Cover image Title page Table of Contents Copyright Preface List of Abbreviations

Constants:

Chapter 1: General Characteristics of Geofluids

Abstract 1.1 Brief History of Geofluid Observation and Research 1.2 Entrapment of Fluids in Minerals 1.3 Basic State Properties of Geofluids 1.4 Changes in Fluid Inclusions

Chapter 2: Phase Diagrams

Abstract 2.1 Unary Systems 2.2 Properties of Water 2.3 Aqueous Systems with Salts 2.4 Aqueous Systems with Gases 2.5 Gas Mixtures 2.6 Hydrocarbons 2.7 Silicate Melt

Chapter 3: Equations of State

Abstract 3.1 Behavior of Ideal Gas 3.2 Equations of State for Geofluids

Chapter 4: Fluid and Melt Inclusion Microthermometry

Abstract 4.1 Observation and Imaging 4.2 Sample Handling and Storage 4.3 Calculating Volumetric Phase Ratios 4.4 Calculating Fluid Inclusion Volumes 4.5 Evaluating Trapping Modes of Fluid Inclusions 4.6 Measuring Temperatures of Phase Transitions Suggested Further Reading

Chapter 5: Interpretation of Microthermometric Data

Abstract 5.1 Calculating Densities and Isochores 5.2 Calculating Fluid and Melt Viscosities 5.3 P–T Estimates 5.4 Calculating Depths and Geothermal Gradients 5.5 Trend Analysis Suggested Further Reading

Chapter 6: Fluid Thermodynamics

Abstract 6.1 Thermodynamic Laws 6.2 Free Energy of Reaction 6.3 Gas Fugacity 6.4 Calculating the Fluid Composition from Thermodynamic Data 6.5 Calculating Phase Diagrams and Mineral-Fluid Equilibria

Chapter 7: Raman and Infrared Spectroscopic Analysis

Abstract 7.1 Fundamentals 7.2 Gases and Their Mixtures 7.3 Aqueous Fluids 7.4 Graphite and Carbonaceous Substances 7.5 Petroleum and Bitumen 7.6 Silicate Melts 7.7 Magmatic Volatiles and Fluxing Species 7.8 Raman Mapping and Modeling

Chapter 8: Miscellaneous Spectrometric and Chromatographic Methods

Abstract 8.1 Crush-Leach Analysis of Aqueous Inclusions 8.2 Bulk Gas Analysis 8.3 Laser Ablation Analysis 8.4 Selected Applications Suggested Further Reading

Chapter 9: Stable Isotope Geochemistry of Geofluids

Abstract 9.1 Terminology and Principles 9.2 Stable Isotope Composition of Geofluid Reservoirs 9.3 Stable Isotopes in Fluid Inclusions 9.4 Stable Isotope Thermometry 9.5 Isotope Fractionation in Open and Closed Systems 9.6 Magmatic Devolatilization–Crystallization 9.7 Hydrothermal Devolatilization–Precipitation 9.8 Fluid–Rock Interaction 9.9 Hydrothermal Alteration 9.10 Fluid Mixing and Infiltration 9.11 Isotope Fractionation Trends in Natural Hydrothermal Carbonates 9.12 Interpretation of Stable Isotopes and Fluid Inclusions in Siderite and Magnesite Deposits of Western Carpathians Suggested Further Reading

Appendix I: Eutectic and Peritectic Points of Aqueous Systems with Salts Appendix II: Selected Equations of State

H2O CO2 CH4 H2O–NaCl H2O–NaCl–KCl H2O–NaCl–KCl–CaCl2 H2O–CH4 H2O–CO2–NaCl CO2–CO–CH4–H2–H2S–N2

Appendix III: Optical Properties of Fluid Inclusion Phases Appendix IV: Stable Isotope Fractionation Factors Appendix V: Raman Bands Sorted by Vibrations Appendix VI: Raman Bands Sorted by Name Appendix VII: Data Sources, Computer Programs, Websites References Index