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Index
CHAPTER 1
Basic concepts
1.1 THE STATE OF A SYSTEM
1.2 OBSERVABLES
1.3 THE SCHRÖDINGER EQUATION
1.4 MANY-PARTICLE SYSTEMS
PROBLEMS 1
CHAPTER 2
Simple examples
2.1 ONE-DIMENSIONAL SQUARE-WELL POTENTIAL
2.2 POTENTIAL BARRIER
2.3 ANGULAR MOMENTUM
2.3.1 Spherical harmonics
2.4 THE STERN–GERLACH EXPERIMENT
2.5 CENTRAL POTENTIAL
2.5.1 Radial wave equation
2.5.2 The hydrogen atom
2.6 MOMENTUM EIGENSTATES
2.6.1 Box normalization
2.6.2 The continuous spectrum
*2.7 HARMONIC OSCILLATOR
PROBLEMS 2
CHAPTER 3
Several observables
3.1 COMPATIBLE OBSERVABLES
3.1.1 Compatibility and commutativity of observables
3.2 CONSTANTS OF THE MOTION
3.3 THE UNCERTAINTY PRINCIPLE
3.3.1 Proof of the uncertainty principle
PROBLEMS 3
CHAPTER 4
Symmetries
4.1 INVERSION
4.2 TRANSLATIONS
4.3 ROTATIONS
4.4 IDENTICAL PARTICLES
4.4.1 The periodic table
PROBLEMS 4
CHAPTER 5
Angular momentum I: theory
5.1 DIRAC NOTATION
5.2 THE ANGULAR MOMENTUM OF A SYSTEM
5.2.1 The basic results
5.2.2 The raising and lowering operators J±.
5.3 SPIN
5.3.1 Matrix representation of spin
5.3.2 Two-component wave functions
5.4 THE ANGULAR MOMENTUM ADDITION THEOREM
5.5 EXAMPLES OF ANGULAR MOMENTUM ADDITION
5.5.1 Two spin particles
5.5.2 Two orbital angular momenta l = 1
5.6 THE GENERAL CASE
5.7 ADDITION OF ANGULAR MOMENTUM FOR ELECTRONS
*5.8 DERIVATION OF THE EIGENVALUES OF J2 AND Jz
PROBLEMS 5
CHAPTER 6
Angular momentum II: applications
6.1 ATOMIC STRUCTURE
6.1.1 Spectroscopic notation
6.1 .2 Atomic multiplets
6.1.3 Spin–orbit interaction
6.2 ELECTRIC DIPOLE SELECTION RULES
6.2.1 Derivation from conservation laws
6.2.2 Hydrogenic systems
6.2.3 Many-electron atoms
6.2.4 Forbidden transitions
*6.3 BELL’S INEQUALITY
PROBLEMS 6
CHAPTER 7
Bound-state perturbation theory
7.1 THE NON-DEGENERATE CASE
7.2 THE HELIUM GROUND STATE
7.3 THE DEGENERATE CASE
*7.4 SPIN-ORBIT INTERACTION
7.4.1 Spin-orbit interaction in hydrogen
7.4.2 The fine structure in hydrogen
7.4.3 The fine structure in many-electron atoms
*7.5 THE ZEEMAN EFFECT
7.5.1 The weak field case: Vmag Vso
7.5.2 The strong field case: Vmag ≫ Vso
7.5.3 Derivation of Eq. (7.68)
PROBLEMS 7
CHAPTER 8
The variational method
8.1 THE GROUND STATE
8.2 SIMPLE EXAMPLES
8.2.1 The ground state of the hydrogen atom
8.2.2 The ground state of the helium atom
8.3 EXCITED STATES
PROBLEMS 8
CHAPTER 9
Time dependence
9.1 INTRODUCTION
9.2 AN EXACTLY SOLUBLE TWO-STATE SYSTEM*
9.3 TIME-DEPENDENT PERTURBATION THEORY
9.4 TIME-INDEPENDENT PERTURBATIONS
9.5 EMISSION AND ABSORPTION OF RADIATION BY ATOMS
9.5.1 Spontaneous emission
9.5.2 Justifying the electric dipole approximation
9.5.3 Line width
PROBLEMS 9
CHAPTER 10
Scattering I: time-dependent approach
10.1 THE CROSS-SECTION
10.2 POTENTIAL SCATTERING
10.2.1 Density of states
10.2.2 Born approximation
10.2.3 Scattering by a screened Coulomb potential
10.3 ELECTRON-ATOM SCATTERING AT HIGH ENERGIES
PROBLEMS 10
CHAPTER 11
Scattering II: time-independent approach
11.1 THE SCATTERING AMPLITUDE
11.2 THE INTEGRAL EQUATION FOR POTENTIAL SCATTERING
11.3 BORN APPROXIMATION
★11.3.1 Validity of Born approximation
11.4 SCATTERING OF IDENTICAL PARTICLES
11.5 PARTIAL WAVES AND PHASE SHIFTS
11.5.1 s-wave scattering by an attractive square-well potential
PROBLEMS 11
CHAPTER 12
The Dirac formalism*
12.1 KETS
12.2 OPERATORS
12.3 PROBABILITY AMPLITUDES
12.4 WAVE MECHANICS REGAINED
12.5 HARMONIC OSCILLATOR
12.6 REPRESENTATIONS
PROBLEMS 12
Hints and solutions to problems
Bibliography
Index
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